Collecting · Classification

Is lepidolite a mica?

Yes. Lepidolite is a lithium mica, but a series name, not a species: the IMA mica report puts it on the trilithionite–polylithionite join. Hardness 2.5 to 4.

Short answer Yes, it is a mica, and a true mica; but lepidolite is a series name, not a mineral species. The species are trilithionite and polylithionite. On a specimen label or collection card, lepidolite is a correct field name for the pink, scaly crystal masses with perfect {001} cleavage and hardness 2.5 to 4 that grow with elbaite, topaz and spodumeneIMA mica report (Rieder et al. 1999), Table 4 Lepidolite: trioctahedral micas on, or close to, the trilithionite–polylithionite join; light micas with substantial lithiumIMA list, September 2026, by script No line contains the word lepidolite. Rows: polylithionite KLi2AlSi4O10F2 (A, 1998 s.p.); trilithionite KLi1.5Al1.5(Si3Al)O10F2 (Rd, 1998 s.p., Sweden)The 2.5 line Rieder et al.: a mica with fewer than 2.5 octahedral cations per formula unit is dioctahedral, with 2.5 or more trioctahedral. Polylithionite and trilithionite 3.0; muscovite 2.0The sheet’s two analyses, worked Pala, California: 2.54 octahedral cations, Li 0.99, Li2O 3.70%. Radkovice, Czech Republic: 2.87, Li 1.48, Li2O 5.42%Lithium, worked Li2O by mass: polylithionite 7.66%, trilithionite 5.61%, muscovite 0Lepidolite (Handbook) Monoclinic; hardness 2.5 to 4; density 2.8 to 2.9 (2.693 calculated); cleavage {001} perfect; flexible, elastic; pink, purple, rose-red, violet-grey; Mineral Group: mica groupDocumented failure Lithium cannot be measured by electron microprobe; the report says failure to establish lithium has caused a number of erroneous identifications

Yes. Lepidolite is a mica: the IMA mica report (Rieder et al. 1999) defines it as trioctahedral micas on or near the trilithionite–polylithionite join, light micas with substantial lithium. It is a series name, not a species; the IMA list has no lepidolite row. The Handbook sheet gives hardness 2.5 to 4, density 2.8 to 2.9.

In short

  • Yes, and the report says which micas. The IMA mica nomenclature report (Rieder et al., Mineralogical Magazine 63, 267–279, 1999) lists lepidolite in its Table 4 of series names: trioctahedral micas on, or close to, the trilithionite–polylithionite join; light micas with substantial lithium. A series name is for incompletely investigated micas; the species are trilithionite and polylithionite.
  • The IMA list agrees. A script over the September 2026 IMA-CNMNC Master List finds no line with the word lepidolite, zinnwaldite or biotite (hydrobiotite aside), and rows for polylithionite, KLi2AlSi4O10F2 (A, 1998 s.p.), and trilithionite, KLi1.5Al1.5(Si3Al)O10F2 (Rd, 1998 s.p., Sweden). Muscovite is a row too, KAl2(Si3Al)O10(OH)2.
  • The 2.5 line, worked. The report calls a mica dioctahedral below 2.5 octahedral cations per formula unit and trioctahedral at 2.5 or more. From the IMA formulas: polylithionite and trilithionite 3.0, muscovite 2.0. The Handbook of Mineralogy lepidolite sheet’s two analyses give 2.54 (Pala, California) and 2.87 (Radkovice, Czech Republic): both trioctahedral.
  • Documented failure: the Pala analysis. It clears the 2.5 line by only 0.04 and carries 0.99 lithium per formula unit, 0.51 short of trilithionite’s 1.5, at 3.70% Li2O against trilithionite’s worked 5.61%. The report’s “close to” has no number. It also warns that lithium cannot be measured by electron microprobe and that failing to establish it has caused a number of erroneous identifications.
  • Weight does not help. Worked as 20 − 20/D on the sheets, a 20.00 g piece reads 12.86 to 13.10 g in water as lepidolite and 12.78 to 13.06 g as muscovite. Colour, light against dark, is the report’s own field division between lepidolite and zinnwaldite.
Is it a lithium mica, and which side of the 2.5 line? Lepidolite against the species and series names around it. Status from the September 2026 IMA list (by script); definitions of series names from Table 4 of the IMA mica report (Rieder et al. 1999); octahedral cations per formula unit and Li2O by mass worked from the IMA formula on standard atomic weights, or read from the Handbook analysis where marked; hardness and density from each Handbook of Mineralogy sheet; in-water weight of a 20.00 g piece worked as 20 − 20/D. There is no Handbook trilithionite sheet (404)
NameIMA listFormula usedOctahedral cations per formula unitDioctahedral or trioctahedral (2.5 line)Li2O by massHardnessDensity20.00 g piece in waterReport’s field description
Lepidolite (series)No rowK(Li,Al)3(Si,Al)4O10(F,OH)2 (Handbook)2.54 (Pala); 2.87 (Radkovice), from the sheet’s analysesTrioctahedral, both3.70%; 5.42% (sheet analyses)2.5 to 42.8 to 2.9; calc. 2.69312.86 to 13.10 gLight micas with substantial lithium
PolylithioniteA, 1998 s.p.KLi2AlSi4O10F23.0Trioctahedral7.66%2 to 32.58 to 2.8212.25 to 12.91 gEnd-member of the lepidolite join
TrilithioniteRd, 1998 s.p., SwedenKLi1.5Al1.5(Si3Al)O10F23.0Trioctahedral5.61%No sheetNo sheet-End-member of the lepidolite join
Zinnwaldite (series)No rowKLiFe2+Al(AlSi3)O10(F,OH)2 (Handbook)3.0 on that formulaTrioctahedralNot worked2.5 to 42.90 to 3.0213.10 to 13.38 gDark micas containing lithium
MuscoviteA, 1998 s.p.KAl2(Si3Al)O10(OH)22.0Dioctahedral02.5 ∥ [001], 4 ⊥ [001]2.77 to 2.8812.78 to 13.06 gA species, not a series
Biotite (series)No row--Trioctahedral (report)----Dark micas without lithium

Is lepidolite a mica or a mineral? What the IMA mica report says

Both answers are partly right: lepidolite is a mica, but the name is a series name, not a mineral species. The IMA mica report, prepared by the Mica Subcommittee appointed by the Commission on New Minerals and Mineral Names and approved by it (Rieder et al., Mineralogical Magazine 63, 267–279, 1999), lists lepidolite in Table 4, Series names: trioctahedral micas on, or close to, the trilithionite–polylithionite join; light micas with substantial lithium. The report says series names are intended for incompletely investigated micas, to be used by field geologists or petrographers, and that once a mica has been studied in detail the end-member names should be preferred.

The IMA list. A script over the September 2026 list (pdftotext -layout, whole-word search) finds no line with the word lepidolite, zinnwaldite, biotite, lithionite or lithia mica; the one biotite substring is hydrobiotite, a separate row. It finds polylithionite, KLi2AlSi4O10F2, A, 1998 s.p., with Denmark (Greenland) as country, and trilithionite, KLi1.5Al1.5(Si3Al)O10F2, Rd, 1998 s.p., Sweden. The Handbook lepidolite sheet files lepidolite in the mica group and ends its Polymorphism & Series line: a group name. The species page lepidolite carries the hardness-bracket check and the two-source check; neither is repeated here.

Is lepidolite a true mica? The interlayer and the 2.5 line

Yes on both of the report’s tests. The report divides micas by the interlayer cation: true micas if more than 50% of the interlayer cations are univalent, brittle micas if more than 50% are divalent. Both lepidolite analyses on the Handbook sheet have potassium, sodium, rubidium and caesium in that position: 100% univalent at Pala and 98.9% at Radkovice, where 0.01 calcium is the only divalent ion. Both are true micas.

The 2.5 line. The report calls a mica dioctahedral if it contains fewer than 2.5 octahedral cations per formula unit and trioctahedral at 2.5 or more. Worked from the IMA formulas: polylithionite Li2 + Al1 = 3.0; trilithionite Li1.5 + Al1.5 = 3.0; muscovite Al2 = 2.0. From the sheet’s analyses: Pala (Al1.50 Li0.99 Mn0.05) = 2.54; Radkovice (Li1.48 Al1.30 Mg0.05 Mn0.03 Fe0.01) = 2.87. The polylithionite sheet’s Mt. Karnasurt analysis, as the sheet groups it, gives 3.06. Lepidolite sits on the trioctahedral side; muscovite on the other.

Lithium, worked. On standard atomic weights, polylithionite is 3.56% lithium (7.66% Li2O) and trilithionite 2.61% (5.61% Li2O). The Radkovice analysis prints 5.42% Li2O and 1.48 lithium per formula unit, beside trilithionite’s 1.5. Lithium-bearing companions such as spodumene are covered on their own pages; petalite’s lithium figures are on is petalite a feldspar.

Where the check fails: the Pala analysis and the missing lithium

The Handbook’s own first lepidolite analysis is a marginal case. The Stewart mine, Pala, California, analysis clears the 2.5 line by 0.04 and carries 0.99 lithium per formula unit, 0.51 short of trilithionite’s end of the join, with 3.70% Li2O. The report’s definition says on, or close to, the join and gives no number for close. This page does not decide whether the Pala material is close enough; it notes that the sheet’s two analyses lie 0.49 lithium apart.

Lithium is easy to miss. The report says lithium, whose concentrations cannot be determined with electron microprobe techniques, is commonly overlooked in wet-chemical analyses because of its low molecular weight, and that failure to establish the concentration of lithium has caused a number of erroneous identifications. A lithium mica without a lithium determination is, in the report’s terms, an incompletely investigated one, and a series name is the honest label.

How do you tell lepidolite from muscovite and zinnwaldite?

Colour is the report’s own field division, and the sheets agree with it. Table 4 calls lepidolite light micas with substantial lithium and zinnwaldite dark micas containing lithium, on or near the siderophyllite–polylithionite join; biotite is dark micas without lithium. The lepidolite sheet prints pink, purple, rose-red, violet-grey, yellowish, white and colourless; the zinnwaldite sheet grey-brown, yellow-brown and pale violet among others. muscovite is a species and dioctahedral.

Weight does not separate them. Worked as 20 − 20/D, a 20.00 g piece reads 12.86 to 13.10 g in water as lepidolite, 12.78 to 13.06 g as muscovite, 12.25 to 12.91 g as polylithionite and 13.10 to 13.38 g as zinnwaldite. The two overlap from 12.86 to 13.06 g. Hardness overlaps too: 2.5 to 4 against muscovite’s 2.5 parallel to [001] and 4 perpendicular to it. Chromium in muscovite, the other common label question, is on is fuchsite mica. The method for weights is on how to measure specific gravity at home.

What should a lepidolite label say?

Lepidolite is a correct field name; trilithionite or polylithionite needs an analysis that includes lithium. The report prefers end-member names once a mica has been studied in detail, and allows the series name before that. A label can carry both, the series name and, where an analysis exists, the species; how to label and catalogue a mineral collection covers adding to an old card without overwriting it. The Handbook lepidolite sheet’s associates include spodumene, elbaite, amblygonite, columbite, cassiterite, topaz and beryl; tourmaline covers the elbaite side. The rest of this section is at the collecting guides. We hold no catalogue and nothing here is offered for sale; the wanted list is the only commercial route.

Questions

Is lepidolite a mica?
Yes. The IMA mica nomenclature report (Rieder et al. 1999) lists lepidolite as a series name for trioctahedral micas on or near the trilithionite–polylithionite join, light micas with substantial lithium.
Is lepidolite a mineral species?
No. The September 2026 IMA list has no lepidolite row; the species are polylithionite and trilithionite. The Handbook lepidolite sheet itself calls it a group name.
What is the difference between lepidolite and muscovite?
Muscovite, KAl2(Si3Al)O10(OH)2, is a species with 2 octahedral cations per formula unit, dioctahedral and lithium-free. Lepidolite is a trioctahedral lithium mica series: 2.54 and 2.87 octahedral cations in the Handbook’s two analyses.
Is lepidolite the same as zinnwaldite?
No. Both are lithium mica series names in the IMA mica report; lepidolite is light and on the trilithionite–polylithionite join, zinnwaldite dark and on the siderophyllite–polylithionite join.
How much lithium is in lepidolite?
It varies along the series. Worked from the IMA formulas, trilithionite is 5.61% Li2O and polylithionite 7.66%; the Handbook’s lepidolite analyses print 3.70% and 5.42%.